2009
DOI: 10.1002/pssc.200880918
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Optical characterization of bulk GaN substrates with c ‐, a ‐, and m ‐plane surfaces

Abstract: Thick free‐standing GaN grown by hydride vapour phase epitaxy and epi‐ready substrates with c ‐, a ‐, m ‐plane surfaces are examined by variable‐temperature photoluminescence (PL), polarized PL and spatially resolved micro‐PL. Both as‐grown samples and polished substrates exhibit linewidth of the donor‐bound exciton emission below 0.7 meV at 2 K indicative of a high structural quality of the material. For as‐grown samples the relative intensity of green (2.4 eV) and red (1.8 eV) deep‐level‐defect emissions are… Show more

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Cited by 8 publications
(6 citation statements)
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“…3͒ or could not be detected at ϳ60 K, 5 the energy barrier E B should be small for both Si and O and process ͑i͒ is dominating in this low temperature range. The ionization energy E d of Si and O are expected to be similar ͑the difference due to the chemical shift is expected to be small as shown in GaN with E d ϳ 30 meV for Si and E d ϳ 33 meV for O͒ 21 and hence the donor ionization process ͑ii͒ will be similarly efficient for both centers. However, the donor activation process ͑iii͒ will be more efficient for Si with a shallower DX − state ͑ϳ0.14 eV below the CBM͒ than for O with a deeper DX − state.…”
mentioning
confidence: 99%
“…3͒ or could not be detected at ϳ60 K, 5 the energy barrier E B should be small for both Si and O and process ͑i͒ is dominating in this low temperature range. The ionization energy E d of Si and O are expected to be similar ͑the difference due to the chemical shift is expected to be small as shown in GaN with E d ϳ 30 meV for Si and E d ϳ 33 meV for O͒ 21 and hence the donor ionization process ͑ii͒ will be similarly efficient for both centers. However, the donor activation process ͑iii͒ will be more efficient for Si with a shallower DX − state ͑ϳ0.14 eV below the CBM͒ than for O with a deeper DX − state.…”
mentioning
confidence: 99%
“…Although this physical phenomenon depends on a number of complicated factors, we believe that the most suitable powerful optical technique to comprehensively investigate it is photoluminescence (PL) spectroscopy. In addition, owing to almost zero internal strain the freestanding GaN substrates offer highly beneficial factors for obtaining reliable data: the spectral width of various exciton emission lines is strongly reduced in this case [15], which enables us to unambiguously identify various exciton lines and thereby obtain a deeper insight into the complicated exciton-phonon interactions.…”
Section: Introductionmentioning
confidence: 99%
“…22 A 4 K -PL spectrum, shown in Fig. 4, exhibits a sharp near band edge ͑BE͒ emission at 3.47 eV with a narrow FWHM of 6.3 meV.…”
mentioning
confidence: 97%