Colored
poly(vinyl chloride) (PVC) was fabricated by femtosecond
laser micromachining without the addition of chemical colorants, eliminating
the concern of leaching dyes and pigments. We determined that the
changes in surface chemistry and surface topography both contribute
to the observed yellow, brown, and black color formation. X-ray photoelectron
spectroscopy (XPS) on the machined samples showed that conjugated
double bonds are liable for the yellow and brown colors, whereas the
presence of oxidized carbon and surface topography contribute to the
black color. Fourier transform infrared spectroscopy (FTIR) indicated
that laser irradiation altered the material’s properties only
near the surface, which left the bulk properties unaltered. Furthermore,
chemical resistance tests showed that some of the samples were able
to withstand the influence of aggressive chemicals and their color
did not fade. Finally, we showed that the fabrication of colored PVC
highly depends on its ablation energy threshold which is affected
by the laser pulse duration and wavelength.