2006
DOI: 10.1021/jp063484f
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Optical CO Gas Sensor Using a Cobalt Oxide Thin Film Prepared by Pulsed Laser Deposition under Various Argon Pressures

Abstract: An optical CO gas sensor was investigated using cobalt oxide thin films prepared by pulsed laser deposition. The cobalt oxide films were deposited on quartz glass and silicon wafer substrates in Ar at 0.07-133 Pa. The morphology and crystal phase of the films were changed by Ar pressure. Sensitivity was estimated as the transmittance change of the film in dry air and at 200 ppm of CO gas ambient at 350 degrees C. The morphology of the films greatly affected the sensing properties. The optimum Ar pressure for c… Show more

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Cited by 83 publications
(52 citation statements)
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“…Porous nanostructured layers have been studied especially in the context of gas sensing materials (Caricato et al, 2009;Nam et al, 2006). PLD offers many advantages compared to other deposition methods, for example easily controllable film composition by deposition parameters, and a good repetition of stoichiometry of the target material in the films deposited on the substrate.…”
mentioning
confidence: 99%
“…Porous nanostructured layers have been studied especially in the context of gas sensing materials (Caricato et al, 2009;Nam et al, 2006). PLD offers many advantages compared to other deposition methods, for example easily controllable film composition by deposition parameters, and a good repetition of stoichiometry of the target material in the films deposited on the substrate.…”
mentioning
confidence: 99%
“…More importantly, the film porosity typically increases with increasing the background gas pressure, as we previously reported. [23] Figure S4 in the Supporting Information depicts amorphous porous TiO 2 nanorod arrays on the colloidal monolayers with a PS sphere size of 350 nm, fabricated by PLD by changing the background gas pressure from 2.0 to 26.8 Pa without further annealing. From these results, we can clearly see that the porosity of the nanorods increases with increasing background gas pressure during the PLD.…”
Section: Resultsmentioning
confidence: 99%
“…Generally, nanocolumns prefer to grow in the normal direction on the substrate during the PLD process. 75 In the PLD process, the desired target (TiO 2 ) is irradiated by a laser beam using an energy level exceeding its threshold in vacuum environment, plasma including ions (Ti 4+ , O 2-, etc. ), molecules, electrons and clusters are released into the PLD chamber from the target.…”
Section: Formation Mechanism Of Hierarchical Micro/nanostructured Arrmentioning
confidence: 99%
“…When the oxygen pressure increased to very high value, 79.8 Pa, the deposited material completely consisted of small nanoparticles or the aggregates of small nanoparticles, and there was no preferential orientation growth. Because when the gas pressure increases to a high value, the plume is compressed into a smaller space in PLD process, and the possibility of collision among ions or atoms in plasma is greatly enhanced, further resulting in a kinetic energy decrease of ions or atoms, which leads to less crystallization and smaller nanoparticle formation 75 . In this strategy, the height of micro/nanostructured unit can be obviously controlled by varying deposition time during PLD process, the height will increase with increase of PLD time.…”
Section: Introductionmentioning
confidence: 99%