2023
DOI: 10.1002/adma.202303272
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Optical Enhancement of Indirect Bandgap 2D Transition Metal Dichalcogenides for Multi‐Functional Optoelectronic Sensors

Riya Dutta,
Arindam Bala,
Anamika Sen
et al.

Abstract: The outstanding electrical and optical properties of two‐dimensional (2D) transition metal dichalcogenides (TMDs) make them attractive nanomaterials for optoelectronic applications, especially optical sensors. However, the optical characteristics of these materials are dependent on the number of layers. Monolayer TMDs have a direct bandgap that provides higher photoresponsivity compared to multilayer TMDs with an indirect bandgap. Nevertheless, multilayer TMDs are more appropriate for various photodetection ap… Show more

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Cited by 43 publications
(9 citation statements)
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References 229 publications
(384 reference statements)
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“…The optical properties of 2D nanomaterials are closely related to their electronic-band structure; spin–orbital interactions significantly influence their optical behavior by altering the light-absorption bandgap. , Reducing the dimensionality of TMDs causes a shift from an indirect to a large direct bandgap, leading to significant changes in their optical properties, including light absorption and emission . The versatility of 2D nanomaterials in interacting with a broad spectrum of light, from near-infrared (NIR) to ultraviolet (UV), makes them suitable for diverse applications such as biosensing and bioimaging .…”
Section: Properties Of 2d Nanomaterials Used In Healthcare Applicationsmentioning
confidence: 99%
“…The optical properties of 2D nanomaterials are closely related to their electronic-band structure; spin–orbital interactions significantly influence their optical behavior by altering the light-absorption bandgap. , Reducing the dimensionality of TMDs causes a shift from an indirect to a large direct bandgap, leading to significant changes in their optical properties, including light absorption and emission . The versatility of 2D nanomaterials in interacting with a broad spectrum of light, from near-infrared (NIR) to ultraviolet (UV), makes them suitable for diverse applications such as biosensing and bioimaging .…”
Section: Properties Of 2d Nanomaterials Used In Healthcare Applicationsmentioning
confidence: 99%
“…2D transition metal dichalcogenides (TMDCs) are layered materials, which are formed by strong in-plane covalent bonding in individual layers, and their electronic and photonic performance is considered promising for future industrial applications. 1,2 Among many 2D TMDCs, WSe 2 has received more research attention due to its unique band gap structure such as an indirect bandgap of ∼1.2 eV in bulk and a direct bandgap of ∼1.5 eV in monolayer. 3 In recent years, the layer-dependent photoluminescence (PL) property of layered WSe 2 has been studied; particularly, as the thickness decreases to a monolayer, the transition from indirect to direct gap has been observed by PL measurements.…”
Section: Introductionmentioning
confidence: 99%
“…In recent past, the use of transition metal dichalcogenides (TMDs) has emerged as a promising technology for developing advanced sensors owing to their unique optical and electrical properties including high carrier mobility, tunable bandgap, and strong light-matter interactions. [1][2][3][4][5] One of the potential applications of TMD-based sensors is visible and infrared photodetection systems in vehicles, computer vision, drones, biomedical imaging, and security surveillance. [6][7][8][9][10] The conventional visible and infrared photodetection system relies on two different spectral range sensors, each optimizing for different lighting conditions.…”
Section: Introductionmentioning
confidence: 99%