“…(2) and (3) increases with the particle radius , and the values of the quantities Im and Im mag become approximately equal to each other at ≈ 2 nm [16].…”
Section: Introductionmentioning
confidence: 84%
“…In the framework of the dipole approximation for monometallic spheres, the absorption, abs , and scattering, sca , cross-sections are determined in terms of the electric, , and magnetic, mag , polarizabilities as follows [1,16,17]:…”
Section: Introductionmentioning
confidence: 99%
“…After the publication of the famous book [19], in which the optical size-dependent properties of monometallic clusters located in various matrices were analyzed, there appeared only a few reports on the results of new measurements in the literature, most likely because of the complicated character of experiments [20][21][22]. Interest in the early works was mainly focused on the absorption by metal particles in the far-infrared spectral interval (see, e.g., works [16,17] and the references therein). Nowadays, the focus of research is aimed at nanoplasmonics, which is associated, first of all, with its applications in biology and medicine.…”
В роботi одержано формулу для часу релаксацiї електронiв на поверхнi i проаналiзовано частотну залежнiсть електричної i магнiтної компонент поляризовностi двошарової металевої нанокулi. Максимуми поляризовностi вiдповiдають плазмонним резонансам ядра та оболонки. Розрахунки було проведено для бiметалевих наночастинок Ag–Au, Au–Ag та Ag–Al, розташованих у тефлонi. Продемонстровано можливiсть керування оптичними характеристиками бiметалевих наночастинок змiною їх морфологiї. Проведено розрахунки перерiзiв екстинкцiї i розсiювання та фактора пiдсилення поля в околi наночастинок у широкому спектральному iнтервалi за рiзних спiввiдношень розмiрiв ядра та оболонки, а також оцiнено температуру бiметалевої нанокулi для фототермiчної терапiї злоякiсних пухлин.
“…(2) and (3) increases with the particle radius , and the values of the quantities Im and Im mag become approximately equal to each other at ≈ 2 nm [16].…”
Section: Introductionmentioning
confidence: 84%
“…In the framework of the dipole approximation for monometallic spheres, the absorption, abs , and scattering, sca , cross-sections are determined in terms of the electric, , and magnetic, mag , polarizabilities as follows [1,16,17]:…”
Section: Introductionmentioning
confidence: 99%
“…After the publication of the famous book [19], in which the optical size-dependent properties of monometallic clusters located in various matrices were analyzed, there appeared only a few reports on the results of new measurements in the literature, most likely because of the complicated character of experiments [20][21][22]. Interest in the early works was mainly focused on the absorption by metal particles in the far-infrared spectral interval (see, e.g., works [16,17] and the references therein). Nowadays, the focus of research is aimed at nanoplasmonics, which is associated, first of all, with its applications in biology and medicine.…”
В роботi одержано формулу для часу релаксацiї електронiв на поверхнi i проаналiзовано частотну залежнiсть електричної i магнiтної компонент поляризовностi двошарової металевої нанокулi. Максимуми поляризовностi вiдповiдають плазмонним резонансам ядра та оболонки. Розрахунки було проведено для бiметалевих наночастинок Ag–Au, Au–Ag та Ag–Al, розташованих у тефлонi. Продемонстровано можливiсть керування оптичними характеристиками бiметалевих наночастинок змiною їх морфологiї. Проведено розрахунки перерiзiв екстинкцiї i розсiювання та фактора пiдсилення поля в околi наночастинок у широкому спектральному iнтервалi за рiзних спiввiдношень розмiрiв ядра та оболонки, а також оцiнено температуру бiметалевої нанокулi для фототермiчної терапiї злоякiсних пухлин.
“…where τ is a relaxation time in the bulk of the metal, caused by electron-electron collisions (τ × 10 14 = 6.23 s for Au at T = 75 K [21]), and v F is the electron velocity at the Fermi surface in the bulk. The estimation performed in [22] gives a preferred electron collision on walls of a dot, therefore τ ε R/v F . This leads to τ ε ε p / h {0.52, 0.17}, i.e.…”
Section: Coulomb Instability Of a Cluster In An Electric Fieldmentioning
The effects of charging and single-electron tunnelling in a metal cluster structure are investigated theoretically. In the framework of the particle-in-a-box model for spherical and disc-shaped gold clusters, the electron spectrum and the temperature dependence of the electron chemical potential are calculated. The difference between the electron chemical potentials of massive electrodes and islands leads to the noticeable charging of the electrode. We show that the effective residual charge is equal to the non-integer value of the elementary charge e and depends on the shape of the cluster. The equations for the analysis of the current-voltage characteristic are used under the conditions of conservation of the total energy of the structure, taking into account the contact potential difference. Restrictions associated with the Coulomb instability of a cluster are introduced into the theory in a simple way. It is shown that the critical charge of the cluster in an open electron system is close to the effective residual charge. For single-electron molecular transistors based on small gold clusters the current gap and its voltage asymmetry are computed. We demonstrate that the current gap exhibits non-monotonic size dependences which are related to the quantization of the electron spectrum and the Coulomb blockade.
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