“…The • C 3 H 3 RSR is the key species in this pathway [47,72,77]. We hypothesise that for aliphatic fuels, the C3 pathway has a high rate [79] and provides a crucial contribution to benzene formation in flames [91,77,92]. It is proposed that is this availability of C1 species and the consequent benzene formation via the C3 pathway, over and above that in the P0 flame, that is thought to be responsible for the synergistic increase in soot production in the P5 flame.…”