“…Thus nanosecond optical parametric oscillators (OPOs) seem to possess the best potential for achieving high average power and single pulse energy. Such OPOs, pumped in the 1 µm range, have been demonstrated, however, only with 5 of the 14 compounds analyzed in [2]: Ag 3 AsS 3 [3][4][5], AgGaS 2 [6][7][8][9], HgGa 2 S 4 [10], LiInSe 2 [11], and the solid solution Cd x Hg 1-x Ga 2 S 4 [12]. Moreover, apart from the archive Ag 3 AsS 3 [5], oscillation at idler wavelengths exceeding 4.4 µm has been demonstrated only with AgGaS 2 [8,9], achieving impressive tunability from 3.9 to 11.3 µm [8].…”