“…Despite the fact that both passive films have similar stoichiometries, the predominance of more oxygen defects between these two oxides can be accounted for the different structure and lattice parameter values. Thus, Nb 2 O 5 has a tetragonal structure with a = 20.01 Å and c = 3; and Ta 2 O 5 is orthorhombic, a = 6.117 Å, b = 3.716 Å, c = 4.114 Å [34][35][36]. This difference in height between two faces in the tetragonal structure could be the explanation behind why the oxygen vacancy diffusivity for the Nb 2 O 5 is higher in comparison with Ta 2 O 5 .…”