1977
DOI: 10.1016/0038-1098(77)90210-1
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Optical properties of F centers in KCN crystal

Abstract: Absorption, excitation and emission spectra of F centers in KCN were measured between 4.5 K and 175 K. Due to the cubic to orthorhombic structural phase transition at 168 K, the F band splits into three components. Their properties in the antiferroelectric phase (T<83 K) are explained by an internal Stark effect due to the local electric field. The single emission band has a decay time of 21.5 neec at 4.5K.

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