A new polymer nanolayer gradient refractive index (GRIN) system with more robust thermal stability because of incorporation of a high glass transition temperature polyester, OKP4HT, was demonstrated. A combination of extruded nanolayered GRIN film systems, comprised of five unique polymer materials, were combined to produce laminate optics comprised of a large internal refractive index gradient distribution, n 5 1.445 -1.630, without degradation of optical transmissive properties. The optical performance of a series of varied magnitude GRIN lenses, ranging from Dn 5 0 to 0.185, was evaluated. Increasing the lens refractive index range resulted in decreased optic sphericalaberrations that followed analytical predictions. An analytical approach was reported to correlate the polymer material upper service temperature (UST) to the onset of polymer material loss modulus as measured by DMTA. Thermo-optical interferometry measurements of irreversible lens deformation confirmed the lenses UST at 1258C for the OKP4HT/ PC system as compared to 758C for a PMM/SAN17 system.