“…Due to their high cost‐effective, since then Fe‐B alloys have been getting more and more interest, and they have been successfully applied to mud pump blade, glass molds [18], roll [19], guide rolls [20], grinding ball [21], hammer head [22] and hot‐dip [23, 24], etc. Recently, Fe 2 B as a functional material has been also shown great application potential in catalysis [25, 26], microwave absorbers [27], magnetic fluid therapy [28], optical controllable magnetic devices [29], strong ferromagnetic material with high hardness [30], etc. As well know, these applications of Fe 2 B are closely related to its fundamental properties such as crystal structure, stability, mechanical, electronic and magnetic properties.…”