Since light fidelity (LiFi) and wireless fidelity (WiFi) do not interfere with one another, a LiFi/WiFi hybrid network may provide superior performance to existing wireless options. With many users and constant changes, a network can easily become overloaded, leading to slowdowns and fluctuations in data transfer speeds. Access point assignment (APA) is required with the increase of users, which can negatively impact the system performance and quality-of-service (QoS) due to mobility and line-of-sight (LOS) blockage. Many variables could influence the APA process; these variables are considered as criteria, such as the network capacity, the degree of blockage, the speed of the connected user, etc. Unlike conditional APA methods, recent studies have considered treating these variables as “evaluation criteria”. Considering these criteria can offer better and more accurate results, eventually enhancing the APA process and QoS. However, the variety of these criteria, the conflict amongst them, their weights (importance), and priority have not been addressed so far. Moreover, treating the criteria equally might result in inaccurate outcomes. Therefore, to solve this issue, it is essential to investigate the impact of each criterion on the APA process. In this work, a multicriteria decision-making (MCDM) problem is formulated to determine a network-level selection for each user over a period of time The decision problem is modeled as a hierarchy that fragments a problem into a hierarchy of simple and small subproblems, and the selection of the AP network among various alternatives is a considered as an MCDM problem. Based on the previous works, we are not aware of any previous research attempts using MCDM methods in the LiFi research area for network selection. Therefore, this work proposes an access point assignment framework using an MCDM approach for users in a hybrid LiFi/WiFi network. The experiment was conducted based on four phases: (i) Five criteria were identified and evaluated with eleven APs (alternatives). The outcome of this phase was used to build the decision matrix and an MCDM was developed and built based on user mobility and blockages with various scenarios using all the criteria; (ii) The analytic hierarchy process (AHP) was employed to identify the criterion of the subjective weights of each criterion and to determine the degree of importance supported by experts’ judgement. Determining the weights in the AHP process considered various investigations, including the consistency ratio (CR) and the AHP consensus indicator, which is calculated using the rank-based maximum likelihood method (RGMM) and Shannon entropy techniques. The VIekriteri-Jumsko KOmpromisno Rangiranje (VIKOR) method is adopted in the selection of the optimal AP for the proper selection of whether a LiFi or WiFi AP must serve the users. The integrated AHP–VIKOR was effective for solving the APA and was the best solution based on using weighted criteria simultaneously. Moreover, the ranking outcomes of the developed integrated AHP–VIKOR approach were evaluated using sensitivity analysis. The result of this work takes the APA for hybrid LiFi networks to a new perspective.