In the field of electrical network, it is necessary, under different conditions, to learn about the behavior of the system. Power Flow Analysis is the tool per excellent that allow as to make a deep study and define all quantities of each bus of the system. To determine power flow analysis there is a lot of methods, we have either numerical or intelligent techniques. Lately, researchers always work on finding intelligent methods that allow them to solve their complex problems. The goal of this article is to compare two intelligent methods that are capable of predicting quantities; Artificial Neural Network and Adaptive Neuro-Fuzzy Inference System using real electrical networks. To do that we used few significant discrepancies. These methods are characterized by giving results in real time. To make this comparison successful, we implemented these two methods, to predict the voltage magnitudes and the voltage phase angles, on two Moroccan electrical networks. The results of the comparison show that the method of Adaptive Neuro-Fuzzy Inference System have more advantages than the method of Artificial Neural Network.