Optimal values of rovibronic energy levels for triplet electronic states of molecular deuterium

Lavrov, B. P.; Umrikhin, I. S.

doi:10.1088/0953-4075/41/10/105103

Cited by 17 publications

(15 citation statements)

References 43 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…IV A. The more precise relative level positions of the high-np Rydberg states of ortho-H 2 derived from this analysis are combined with experimental data on low-n states of H 2 and D 2 from the literature [21][22][23][24][25][26][27][28][29][30][31][32][33] to obtain improved eigenquantum-defect parameters in a weighted global fit, as described in Sec. IV B.…”

Section: Introductionmentioning

confidence: 99%

Determination of the binding energies of the np Rydberg states of H2, HD, and D2 from high-resolution spectroscopic data by multichannel quantum-defect theory

Sprecher

Jungen

Merkt

2014

The Journal of Chemical Physics

View full text Add to dashboard Cite

Multichannel quantum-defect theory (MQDT) is used to calculate the electron binding energies of np Rydberg states of H2, HD, and D2 around n = 60 at an accuracy of better than 0.5 MHz. The theory includes the effects of rovibronic channel interactions and the hyperfine structure, and has been extended to the calculation of the asymmetric hyperfine structure of Rydberg states of a heteronuclear diatomic molecule (HD). Starting values for the eigenquantum-defect parameters of MQDT were extracted from ab initio potential-energy functions for the low-lying p Rydberg states of molecular hydrogen and subsequently refined in a global weighted fit to available experimental data on the singlet and triplet Rydberg states of H2 and D2. The electron binding energies of high-np Rydberg states derived in this work represent important quantities for future determinations of the adiabatic ionization energies of H2, HD, and D2 at sub-MHz accuracy.

show abstract

Section: Introductionmentioning

confidence: 99%

Determination of the binding energies of the np Rydberg states of H2, HD, and D2 from high-resolution spectroscopic data by multichannel quantum-defect theory

Sprecher

Jungen

Merkt

2014

The Journal of Chemical Physics

View full text Add to dashboard Cite

show abstract

“…At present almost all available experimental data on rovibronic line wavenumbers of H 2 and D 2 molecules were obtained from emission spectra by photographic recording. Our recent studies revealed that these data have significant differences with values predicted by Rydberg-Ritz combination principle as well as with fragmentary experimental data obtained by laser induced fluorescence and with our own emission spectroscopy data obtained with photoelectric recording by matrix detectors [1,2]. The minority of the differences is caused by misprints and erroneous line assignments; they may amount to several wavenumbers.…”

Section: St-petersburg 198904 Russiamentioning

confidence: 63%

New sets of experimental wavenumber values for triplet-triplet rovibronic transitions of $H_2$ and $D_2$

Lavrov¹,

Mikhailov²,

Umrikhin³

2010

Preprint

View full text Add to dashboard Cite

“…Detailed description of the analysis will be provided elsewhere. The analysis is similar to that described in our previous work [11], but the observation of pseudo doublets [12] forced us to carry out the optimization in two stages. At the first stage spectral line wavenumber values for band systems having one common low electronic state a 3 Σ + g (n 3 Λ g → a 3 Σ + g , with Λ = 0, 1 and n = 3 − 9) were analyzed.…”

mentioning

confidence: 82%

“…7011 17842. 12(3) 819( 16) T+ 3c-2a (3-2) R4 7040 17822.26 (3) 53.1 (11) 7012 17841.87 (4) 178 (13) 7041 17821.89 (3) 39.7 (8) 7013 17841.58 (4) 63( 4) S+ GK-2B (1-4) R4 7042 17821.07 (3) 140. 3(18) 7014 17840.83 (3) 94.…”

mentioning

confidence: 99%

See 1 more Smart Citation

Atlas and wavenumber tables for visible part of the rovibronic multiline emission spectrum of the $D_2$ molecule. II. Wavenumber range $18161 ÷14379$ cm$^{-1}$ measured with moderate resolution

Lavrov,

Umrikhin

2012

Preprint

View full text Add to dashboard Cite

show abstract

Optimal values of rovibronic energy levels for triplet electronic states of molecular deuterium

Cited by 17 publications

References 43 publications

Determination of the binding energies of the np Rydberg states of H2, HD, and D2 from high-resolution spectroscopic data by multichannel quantum-defect theory

Determination of the binding energies of the np Rydberg states of H2, HD, and D2 from high-resolution spectroscopic data by multichannel quantum-defect theory

New sets of experimental wavenumber values for triplet-triplet rovibronic transitions of $H_2$ and $D_2$

Atlas and wavenumber tables for visible part of the rovibronic multiline emission spectrum of the $D_2$ molecule. II. Wavenumber range $18161 ÷14379$ cm$^{-1}$ measured with moderate resolution

Contact Info

Product

Resources

About