The n-book embedding of a graph G is an embedding of the graph G in an n-book with the vertices of G on the spine and each edge to the pages without crossing each other. If the degree of vertices of G at most one in each page, the n-book embedding is matching. The matching book thickness of graph G is the smallest n so that G can be matching embedded in an n-book. In this paper, the matching book thickness of the biconnected outerplanar graphs is determined.