The evaluation studies need to investigate a determined performance metrics to understand and evaluate the examined scenarios. SIP-based Voice over IP (VoIP) applications over MANET, which behaves in a way similar to Direct Mode of Operation (DMO) in mission Critical Communication Systems, have two main performance categories related to the Quality of Service (QoS). The main performance metrics that are considered for the evaluation processes in this research are the SIP end-to-end Performance metrics as defined by the RFC 6076. The main performance metrics are related to the registration, the call setup, and the call termination processes. In this research study, the SIP performance metrics are based on a single SIP proxy server. For voice data, the QoS evaluation is based on two methods: The Objective method and the Subjective method. The Objective method considers the traffic throughput, end-to-end delays, packet loss, and jitter, while the subjective method considers the Mean Opinion Score (MOS), which is mostly related to the end users' experiences during voice calls.