Abstract. Numerical methods based upon the Riemann Problem are considered for solving the general initial-value problem for the Euler equations applied to real gases. Most of such methods use an approximate solution of the Riemann problem when real gases are involved. These approximate Riemann solvers do not yield always a good resolution of the flow field, espe~zially for contact surfaces and expansion waves. Moreover, approximate Riemann solvers cannot produce exact solutions for the boundary points. In order to overcome these shortcomings, an exact solution of the Riemann problem is developed, valid for real gases. The method is applied to detonation products obeying a 5th order virial equatioa of state, in the shock-tube test case. Comparisons betwe,~n our solver, as implemented in Randorn Choice Method, and finite difference methods, which do not employ a Riemann solver, are given.