“…Various ceramic materials have been tried for reducing hydrogen isotope permeation, such as Al 2 O 3 , Cr 2 O 3 , Er 2 O 3 , ZrO 2 , Y 2 O 3 , SiC, TiC, and TiN 8–10 . Among these ceramics, α‐Al 2 O 3 is the most promising HPB candidate because of its much higher hydrogen resistance, high electrical resistivity, combined with excellent thermal and chemical stability 11–15 . Several technologies have been adopted to fabricate Al 2 O 3 coatings, including pack cementation aluminizing, 16 chemical vapor deposition, 17 ionic liquid plating, 18,19 metal‐organic decomposition, 20,21 and sol–gel 22,23 .…”