The article explores innovative methods for creating high-insulation walls, essential for the future of energy-efficient and sustainable construction. It focuses on advanced 3D-printing technologies that allow for the construction of walls with superior insulation materials, optimizing thermal properties and significantly reducing energy for heating and cooling. The integration of thermal insulation within wall structures and innovations in building materials like lightweight composites, aerogels, and nanotechnology-based insulations are highlighted. It discusses the environmental, economic, and technical benefits of these innovations and the challenges to fully leverage 3D printing in construction. Future development directions emphasize materials that enhance thermal efficiency, sustainability, and functionality, promising a new era of sustainable and innovative construction practices.