Geopolymer concrete, because of its less embodied energy as compared to conventional cement concrete, has paved the way for achieving sustainable development goals. In this study, an effort was made to optimize its quality characteristics or responses, namely, workability, and the compressive and flexural strengths of Ground Granulated Blast-furnace Slag (GGBS)-based geopolymer concrete incorporated with polypropylene (PP) fibers by Taguchi’s method. A three-factor and three-level design of experiments was adopted with the three factors and their corresponding levels as alkali ratio (NaOH:Na2SiO3) (1:1.5 (8 M NaOH); 1:2 (10 M NaOH); 1:2.5 (12 M NaOH)), percentage of GGBS (80%, 90%, and 100%) and PP fibers (1.5%, 2%, and 2.5%). M25 was taken as the control mix for gauging and comparing the results. Nine mixes were obtained using an L9 orthogonal array, and an analysis was performed. The analysis revealed the optimum levels as 1:2 (10 molar) alkali ratio, 80% GGBS, and 2% PP fibers for workability; 1:2 (10 molar) alkali ratio, 80% GGBS, and 2.5% PP fibers for compressive strength; and 1:2 (10 molar) alkali ratio, 80% GGBS, and 1.5% PP fibers for flexural strength. The percentage of GGBS was found to be the most effective parameter for all three responses. The analysis also revealed the ranks of all the factors in terms of significance in determining the three responses. ANOVA conducted on the results validated the reliability of the results obtained by Taguchi’s method. The optimized results were further verified by confirmation tests. The confirmation tests revealed the compressive and flexural strengths to be quite close to the strengths of the control mix. Thus, optimum mixes with comparable strengths were successfully achieved by replacing cement with GGBS and thereby providing a better path for sustainable development.