Hydrogeological characterization is required when investigating contaminated sites, and hydraulic conductivity is an important parameter that needs to be estimated. Before groundwater sampling, well water level values are measured during low-flow purging to check the correct driving of the activity. However, these data are generally considered only as an indicator of an adequate well purging. In this paper, water levels and purging flow rates were considered to estimate hydraulic conductivity values in an alluvial aquifer, and the obtained results were compared with traditional hydraulic conductivity test results carried on in the same area. To test the applicability of this method, data coming from 59 wells located in the alluvial aquifer of Malagrotta waste disposal site, a large area of 160 ha near Rome, were analyzed and processed. Hydraulic conductivity values were estimated by applying the Dupuit’s hypothesis for steady-state radial flow in an unconfined aquifer, as these are the hydraulic conditions in pumping wells for remediation purposes. This study aims to show that low-flow purging procedures in monitoring wells—carried out before sampling for groundwater characterization—represent an easy and inexpensive method for soil hydraulic conductivity estimation with good feasibility, if correctly carried on.