We identify favorable parameters for the formation of
aromatics
from ethanol-based feeds over ZSM-5. An ethanol partial pressure of
0.3 bar, a reaction temperature of ∼700 K, a low weight hourly
space velocity (WHSV), and a high Brønsted acid site density
increase the content of aromatics, in the latter case, on the expense
of lifetime. The aromatic fraction composition changes with the WHSV
and n
Si/n
Al ratio. Water cofeed increases the content of aromatics in the C2:H2O stoichiometry of 1:0.5 (equals diethyl ether
as feed) but decreases it if this is exceeded. Diethyl ether and ethylene
lead to more aromatics than ethanol feed. The lifetime until deactivation
increases in the order ethanol < diethyl ether < ethylene. This
points at different reaction and/or deactivation mechanisms in converting
the three feeds. Thus, a water-poor feed effectively improves the
catalyst lifetime and productivity in the ethanol conversion to aromatics.