This paper emphasised the importance of proper handling and selection of specialised skimmer equipment for accidental pollution with oils. The research was motivated by the lack of similar papers that offer an extensive and recent literature analysis related to the use of skimmers, with the ultimate aim to present the methodology for proper selection of appropriate pollution equipment. Knowledge on the equipment characteristics such as capacity, selectivity, speed, and pump power of the skimmer is essential for efficient and fast collection of spills. The study aimed to calculate the oil collection rate of an individual skimmer device with different pumps. The classification of skimmers, pumps, and collecting tanks was made according to their main features. The results showed the correlation between pump capacity and the skimmers. Due to the complexity of mechanical equipment and various devices, it was crucial to identify and connect the skimmer with the proper pump. For these reasons, the authors proposed a model which determines the optimal combination for thirteen skimmers and eleven pumps. The model can help shorten the time of collecting oil from the sea surface and provide a more efficient and smoother response in the events of accidental marine pollution.