Ultra‐wideband (UWB) is a well‐known radio technology whose media access control (MAC) protocol, WiMedia MAC, has considerable potential to ensure high‐speed and high‐quality data communication for wireless personal area networks. However, these benefits involve a heavy computational workload, thereby posing a challenge to the conventional very‐large‐scale integration (VLSI) approach in terms of providing the required performance and power efficiency. Therefore, this study aims to optimise the VLSI implementation of the WiMedia MAC system by proposing a hybrid shared‐memory and message‐passing multiprocessor system‐on‐chip (MPSoC) architecture. The proposed solution combines the state‐of‐the‐art MPSoC technology and application‐specific instruction‐set processor techniques to (i) accelerate the MAC protocol at task level by using parallel processing, (ii) enable the using of custom instructions to optimise the inter‐processor communication by using an explicit message passing mechanism, and (iii) ease the implementation process by using a high‐level software/hardware co‐design methodology. The proposed platform is implemented on both system‐level SystemC for architecture exploration and standard‐cell technology for future chip implementation. Experimental results show that the proposed hybrid MPSoC architecture achieves 24% performance improvement and 22% power savings over the conventional shared‐memory‐only one.