The construction of the underwater Internet of Things (UIoT) is crucial to marine resource development, environmental observation, and tactical surveillance. The underwater optical wireless communication (UOWC) system with its large bandwidth and wide coverage facilitates the high-capacity information interconnection within the UIoT networks over short and medium ranges. To enhance the coverage characteristics of the UOWC system, an optimized lemniscate-compensated layout of light-emitting diode (LED) array is proposed in this paper, which can ameliorate the received optical power and reliability at the receiving terminal. Compared with traditional circular and rectangular layouts, the received optical power and bit error rate (BER) performance of the proposed system are analyzed based on the Monte Carlo simulation method. The analysis results show that the proposed LED array achieves a smaller peak power deviation and mean square error of the received optical power under three typical seawater environments. Furthermore, the proposed LED-array scheme supports a better BER performance of the UOWC system. For example, in turbid seawater with a transmission depth of 9.5 m, the BER of the proposed LED array layout is 1 × 10−7, which is better than the BER of 3.5 × 10−6 and 1 × 10−4 under the other two traditional light source layouts.