This research investigates the use of municipal solid waste cremated fly ash as a viable substitute for natural sand in building methodologies, with a focus on sustainability. The waste material is used in the manufacturing of concrete roof tiles that are combined with solar PV systems, providing advantages in terms of both thermal comfort and improved energy efficiency. These tiles exhibit thermal insulation prowess by effectively preserving a 2-degree temperature differential and collecting heat from solar panels to enhance their energy-production efficiency. In order to enhance performance even further, aluminium foil is strategically placed on all four sides of the roof walls. The foil acts as a reflector, redirecting solar energy towards the tiles, which leads to a 5% boost in power generation. Particular alignments, such as positioning in an east-west or north-south direction, result in further enhancements in performance of 4% and 3%, respectively. This comprehensive approach not only confirms the use of waste materials for environmentally friendly construction but also emphasizes their crucial role in promoting energy-efficient building methods.