Studies
on carbon fiber (CF)/poly(ether ether ketone) (PEEK) fiber
hybrid textiles were initiated several decades ago because their flexibility
and conformability make them a promising alternative to traditional
prepregs. The adhesion between the CFs and PEEK is mostly controlled
by their inherent surface properties and mutual wettability. However,
details of these properties remain largely unknown, especially those
of PEEK. Therefore, to determine the surface and interfacial properties
of these fibers, we performed a comprehensive study and characterized
their surface topography (atomic force microscopy, scanning electron
microscopy), surface chemistry [X-ray photoelectron spectrometry (XPS),
acid–base titration], surface energies (wetting tests, acid–base
approach), and interfacial mechanical properties [droplet test, interfacial
shear strength (IFSS)]. These experiments were complemented by a theoretical
approach to the prediction of the surface energy components (parachor)
and contact angles of PEEK. We found good agreement between the results
obtained by XPS and wetting tests (base-to-acid surface energy component
ratio), as well as between the predicted and measured surface energy
and contact angles. The results highlight the consistency and reliability
of the proposed methodology. We found that both CFs and PEEK fibers
appear to be smooth at the nanoscale and have large dispersive and
basic surface energy components. The IFSS of CF/PEEK is significantly
higher (44.87 ± 5.76 MPa) compared to that of other thermoplastic
systems. The findings not only demonstrate the potential of CF/PEEK
hybrid textiles but also emphasize the need to further increase the
compatibility between CFs and PEEK fibers by increasing the acidic
component of CF surfaces. Surface treatments and the design of a suitable
sizing are potential methods to achieve this objective in future studies.