Abstract. Spectroscopy of the hydroxyl (OH) airglow has been a
commonly used way to remotely sense temperatures in the mesopause region for
many decades. This technique relies on the OH rotational state populations
to be thermalized through collisions with the surrounding gas into a
Boltzmann distribution characterized by the local temperature. However,
deviations of the rotational populations from a Boltzmann distribution
characterized by a single temperature have been observed and attributed to
an incomplete thermalization of the OH from its initial, non-thermodynamic-equilibrium distribution. Here we address an additional cause for the
apparent amount of excess population in the higher rotational levels of the
OH airglow brought about by integrating these OH emissions through vertical
gradients in the atmospheric temperature. We find that up to 40 % of the
apparent excess population, currently attributed to incomplete
thermalization, can be due to the vertical temperature gradients created by
waves. Additionally, we find that the populations of the different upper
vibrational levels are affected differently. These effects need to be taken
into account in order to assess the true extent of non-thermodynamic-equilibrium effects on the OH rotational populations.