Polyaniline polymer has been prepared by chemical oxidationpolymerization method in laboratory successfully. The PANI and(PVA+PVP) as a polymer blends in different percentage (30%, 50%,70%) from Polyaniline was prepared. The sample was studies asoptical properties by UV-vis spectrophotometer at (400-700) nm.The result of optical energy gap was 2.23 eV for pure (PVA+ PVP)and with additive was increasing with increasing PANI concentrationto become (2.49 for 30% to 2.52 for 70%) PANI. The goal of thisproject is prepare triple blend polymer and study the effect when addconductive polymer (Polyaniline) on the optical properties andcalculate optical constant as energy gap, refractive index, dielectricconstant and dielectric losses for (PVA+PVP) blends.