Ethyl acetate (EA) is an extensively used industrial
solvent, and
typically, aqueous mixtures containing EA are discarded as hazardous
waste. The recovery of EA from wastewater streams would have significant
environmental benefits and be a circular economy approach to solvent
recycling. However, with a relatively high water solubility (8.3%
w/v at room temperature), it remains a challenge. In this paper, we
report the recovery of EA from water using air-sparged sweep gas membrane
distillation (AS-SGMD) with carbon nanotube-immobilized membranes.
A central composite rotatable design was used to study the effect
of process parameters on flux and selectivity via conventional SGMD
and AS-SGMD. The experiments were run at different operating conditions
of temperature, concentration, and flow rate. The flux reached as
high as 1.41 kg/m2 h–1, and selectivity
as high as 10.8 was obtained. The introduction of air sparging improved
the flux by as much as 12% and the selectivity by 17%. The response
surfaces of flux and selectivity as a function of operating variables
were studied, and regression models were developed. For both regular
SGMD and AS-SGMD, the selectivity of EA recovery followed a quadratic
model, while the flux showed a linear response. The predicted and
experimental responses were in agreement with a R
2 value of 0.94. The optimization efforts showed that
relatively low temperatures, higher concentrations, and high flow
rates favored higher selectivity.