There is abundant shale oil in the ocean and on land. Due to the tight lithology of the reservoir, volume fracturing technology is needed to improve the oil and gas productivity. It is very important to study the expansion law of multiple natural fractures in rock masses and its influencing factors in the process of volume fracturing for the formation of fracture networks. Based on the theory of online elastic fracture mechanics, the calculation method of the stress intensity factor at the end of any I–II composite fracture is established by using effective shear stress and considering the influence of T-stress. The calculation model of the stress intensity factor of any fracture on the main fracture wall or the horizontal section of the main fracture wall is established according to the concrete stress conditions in the process of hydraulic fracturing. Based on the principle of stress superposition, the combined interference stress calculation model of fracture ends is established for the case of multiple penetrating cracks in infinite-plane rock masses. Based on the theory of shear failure and plane strain, a model of the initiation direction and condition of natural cracks on the horizontal section of the main fracture wall and both sides of the main fracture in brittle rock is established when there are many coaxial natural cracks under the action of remote site stress and water pressure on the fracture surface. According to the simulation results, on the main fracture wall, when σH > σv > σh or σH > σh > σv, when the crack angle (CA) is within a certain range and multiple natural cracks (MNC) exist, the required pressure for shear failure decreases. When the fracture angle exceeds a certain size, the required pressure increases. When there are MNC in the horizontal or perpendicular sections of the rock mass on both sides of the main fracture, the required net pressure for shear failure decreases within a certain CA range. When the CA exceeds a certain range, it increases or remains basically unchanged. On the whole, the presence of MNC reduces the net pressure for shear failure, which is conducive to the formation of fracture networks.