As more renewable, yet volatile, forms of energy like solar and wind are being incorporated into the grid, the problem of finding optimal control policies for energy storage is becoming increasingly important. These sequential decision problems are often modeled as stochastic dynamic programs, but when the state space becomes large, traditional (exact) techniques such as backward induction, policy iteration, or value iteration quickly become computationally intractable. Approximate dynamic programming (ADP) thus becomes a natural solution technique for solving these problems to near-optimality using significantly fewer computational resources. In this paper, we compare the performance of the following: various approximation architectures with approximate policy iteration (API), approximate value iteration (AVI) with structured lookup table, and direct policy search on a benchmarked energy storage problem (i.e., the optimal solution is computable).