The composition, the surface morphology, and the crystalline and electronic structure of МоО 3 nanofilms are studied using a set of methods, namely, scanning electron spectroscopy and high energy electron diffraction, photoelectron spectroscopy, and secondary electron emission. These nanofilms are obtained by implanting ions into a Mo single crystal heated to Т = 850 K. Films with different thicknesses (~30, 60, and 90 Å) are obtained at an ion energy of 1-5 keV and a dose of D = (4-8) × 10 17 cm-2. It is shown that a continuous and homogeneous polycrystalline МоО 3 film with a surface roughness of at most 1.5 nm is formed. The band gaps of these films are ~3.4 eV, and the widths of the conduction bands are 4.5 eV. It is discovered that there are four maxima of the density of electronic states in the valence band; probably, they are due to hybridization of the N 5 , N 45 , N 4 energy levels of Mo with the L 2 , L 23 , and L 3 energy levels of oxygen.