Nanostructured
In2Se3 compounds have been
widely used in electronics, optoelectronics, and thermoelectrics.
Recently, the revelation of ferroelectricity in low-dimensional (low-D)
In2Se3 has caused a new upsurge of scientific
interest in nanostructured In2Se3 and advanced
functional devices. The ferroelectric, thermoelectric, and optoelectronic
properties of In2Se3 are highly correlated with
the crystal structure. In this review, we summarize the crystal structures
and electronic band structures of the widely interested members of
the In2Se3 compound family. Recent achievements
in the preparation of low-D In2Se3 with controlled
phases are discussed in detail. General principles for obtaining pure-phased
In2Se3 nanostructures are described. The excellent
ferroelectric, optoelectronic, and thermoelectric properties having
been demonstrated using nanostructured and heterostructured In2Se3 with different phases are also summarized.
Progress and challenges on the applications of In2Se3 nanostructures in nonvolatile memories, photodetectors, gas
sensors, strain sensors, and photovoltaics are discussed in detail.
In the last part of this review, perspectives on the challenges and
opportunities in the preparation and applications of In2Se3 materials are presented.