Articles you may be interested inStructural, electrical, magnetic, and thermal studies of Cr-doped La 0.7 Ca 0.3 Mn 1 − x Cr x O 3 ( 0 ≤ x ≤ 1 ) manganites J. Appl. Phys. 107, 083905 (2010); 10.1063/1.3342462 Effect of Li doping on the magnetotransport properties of La 0.7 Ca 0.3−y Li y MnO 3 system: Decrease of metal-insulator transition temperature Variable-range hopping conductivity and absence of a true metal-insulator transition in La 0.7−δ Ca 0.3 Mn 1−y Fe y O 3The structure, ionic valences, magnetism, and magneto-transport behaviors of mixed valence oxides La 1Àx Ca x Mn 1Àx Ru x O 3 are systematically investigated. The simultaneous substitutions of La 3þ and Mn 3þ ions by Ca 2þ and Ru 4þ , respectively, are confirmed by the structural and ionic valence characterizations, excluding the presence of Mn 4þ and Ru 3þ ions. The enhanced ferromagnetism, induced metal-insulator transition, and remarkable magnetoresistance effect are demonstrated when the substitution level x is lower than $0.6, in spite of the absence of the Mn 3þ -Ru 4þ e g -orbital double-exchange. These anomalous magnetotransport effects are discussed based on the competing multifold interactions associated with the Mn 3þ -Ru 4þ super-exchange and strong Ru 4þ -Ru 4þ hopping, while the origins for the metal-insulator transition and magnetoresistance effect remain to be clarified. V C 2014 AIP Publishing LLC.