Organic aspects. Oxygen-containing functions

Abstract

In this chapter, most of the reported work deals with the photochemistry of carbonyl compounds; however, the photoreactions of other functions, such as the photo-Claisen rearrangement or the photocleavage of cyclic ethers, are also included. In the present volume, time coverage is 2010–2011, and only original research articles are quoted. In general, reviews or purely theoretical calculations are not systematically included. As usually, the material is organized according to established types of reactions (e.g., Norrish I/II, hydrogen abstraction, Paternò-Büchi, photoelimination, photo-Fries/photo-Claisen, etc.). After presenting the basic photochemical aspects, more specific findings are reported. They include synthetic applications, stereoselectivity, and biological or technological implications. Next, the attention is focused on photochemical reactions in anisotropic media, including (micro)heterogeneous or supramolecular systems, solid matrixes or fully organized crystals. Finally, mechanistic studies based on direct experimental evidence are highlighted, especially when transient absorption spectroscopy or related ultrafast detection are employed.