Million years old Ultisols, developed as an end stage of advance soil weathering on base-poor rock systems under forest and plantation crops of the Indian sub-continent, are enriched with organic carbon (OC). Despite their remarkable acid chemical reaction, they show an upward increase in extractable bases (EB) and base saturation (BS) in the pedon, and on some occasion BS > 35% in surface horizons. Recent research suggests that the litter falls from forest species provide bases on soil surface, which causes similar depth distribution of EB and BS in Andisols of Nilgiri Hills of humid tropical southern India, developed on pre-weathered lateritic materials consisting primarily of Fe and Al oxides/ hydroxides. Under similar humid tropical (HT) climate in protected rain forest, million years old OC rich soils of Andaman and Nicobar Islands, developed on base-poor rock systems, have similar chemical and clay mineralogical properties of Ultisols except however their EB and BS, which are more than 10% and much above 50%, respectively and therefore, they are acidic Alfisols. Formation of Alfisols on the Island is a unique example on the formidable role of vegetation in soil formation, suggesting that if inland Ultisols are kept under natural protected forest ecosystem, they may phase towards Alfisols thereby facilitating OC sequestration and perform other ecosystem functions. The preservation of natural or semi-natural ecosystems is thus essential to raise the OC stocks of soils, which would help to gain various ecological benefits.