All rights reserved. No part of this periodical may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, recording, or any information storage and retrieval system, without permission in writing from the publisher. Permission for printing and for reprinting the material contained herein has been obtained by the publisher. Abbreviations: MAP, mean annual precipitation; PDI, profile development index; PET, potential evapotranspiration; SCM, Santa Catalina Mountains; SOC, soil organic carbon. I n the hot, dry ecosystems of the southwestern United States, water availability and topography are central to understanding soil and landscape evolution. Water availability is the dominant driver of soil formation in water-limited climates where precipitation regulates soil production and erosion, vegetation distribution and primary production, soil organic C (SOC) storage, and the degree of primary mineral alteration to secondary products. Topography and landscape position are particularly important in water-limited systems through their control on the redistribution of limited water resources that can lead to significant variation in hillslope-scale soil development and physiochemical properties (Muhs, 1982). It is necessary to understand the coupling of soil, climate, and landscape position in the Desert Southwest where predicted changes in temperature extremes and precipitation variability may drive significant shifts in water availability and biological production (Seager et al., 2007; Intergovernmental Panel on Climate Change,