Organic chemistry of dichlorosilane. Additions to conjugated and unconjugated diene systems followed by intramolecular cyclizations

Functionalized regio-regular linear polyethylenes from the ROMP of 3-substituted cyclooctenes

“…The hydrosilylation at the 3 position was expected if taken into account that the isomerization of cyclic dienes from non-conjugated to conjugated dienes has been previously reported using H 2 PtCl 6 [60]. Based on NMR\5 % of 5-substituted COE monomer was obtained using this method.…”

Custom Hydrosilane Synthesis Based on Monosilane

“…Another documented solution to the problem is stepwise transition-metal-catalyzed hydrosilylation of unsaturated hydrocarbons with dichlorosilane, obtainable in bulk quantities. [2][3][4][5] The accumulation of salt waste is another penalty often encountered when converting the aforementioned silanes into the corresponding hydrosilanes by hydride reduction, typically with LiAlH 4 ( Figure 1A). What is missing is the custom synthesis of hydrosilanes R 4-n SiH n , where n = 3, 2, and 1, based on the simplest silicon molecule, i.e., monosilane, as a platform.…”

Synthesis and characterization of 1-methyl-1-silaindane and 1-methyl-1-germaindane

“…The bicyclic indane structure is particularly appealing for numerous applications alluded to above, and control over the R and R 0 groups could tailor the system for the particular purpose. A few silaindanes have been reported, most of which are symmetrically substituted at Si [8][9][10][11]. The only germaindane reported is the symmetric 1,1-dimethyl-1-germaindane [12,13].…”