Organic Compounds of Bismuth: Synthesis, Structure, and Applications

Шарутин, В. В.; Poddel’sky, Andrey I.; Шарутина, О. К.

doi:10.1134/s1070328421120022

Russ J Coord Chem

2021

DOI: 10.1134/s1070328421120022

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Organic Compounds of Bismuth: Synthesis, Structure, and Applications

В. В. Шарутин

Andrey I. Poddel’sky

О. К. Шарутина

Abstract: The present review, describing the modern achievements in the area of synthetic methods, investigation of specific structural features, and possibilities of practical use of the organic compounds of bismuth, is based on an analysis of the scientific literature published from 2010 to 2020. Some earlier works are also reviewed due to their significance. The bibliography consists of 190 references.

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Cited by 2 publications

References 187 publications

(200 reference statements)

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Construction of High‐Performance Anode of Potassium‐Ion Batteries by Stripping Covalent Triazine Frameworks with Molten Salt

Zhang,

Fu,

Qiu

et al. 2024

Advanced Science

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Covalent triazine frameworks (CTFs) are promising battery electrodes owing to their designable functional groups, tunable pore sizes, and exceptional stability. However, their practical use is limited because of the difficulty in establishing stable ion adsorption/desorption sites. In this study, a melt‐salt‐stripping process utilizing molten trichloro iron (FeCl3) is used to delaminate the layer‐stacked structure of fluorinated covalent triazine framework (FCTF) and generate iron‐based ion storage active sites. This process increases the interlayer spacing and uniformly deposits iron‐containing materials, enhancing electron and ion transport. The resultant melt‐FeCl3‐stripped FCTF (Fe@FCTF) shows excellent performance as a potassium ion battery with a high capacity of 447 mAh g−1 at 0.1 A g−1 and 257 mAh g−1 at 1.6 A g−1 and good cycling stability. Notably, molten‐salt stripping is also effective in improving the CTF's Na+ and Li+ storage properties. A stepwise reaction mechanism of K/Na/Li chelation with C═N functional groups is proposed and verified by in situ X‐ray diffraction testing (XRD), ex‐situ X‐ray photoelectron spectroscopy (XPS), and theoretical calculations, illustrating that pyrazines and iron coordination groups play the main roles in reacting with K+/Na+/Li+ cations. These results conclude that the Fe@FCTF is a suitable anode material for potassium‐ion batteries (PIBs), sodium‐ion batteries (SIBs), and lithium‐ion batteries (LIBs).

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Construction of High‐Performance Anode of Potassium‐Ion Batteries by Stripping Covalent Triazine Frameworks with Molten Salt

Zhang,

Fu,

Qiu

et al. 2024

Advanced Science

View full text Add to dashboard Cite

show abstract

Synthesis and Structure of Tetraphenylphosphorus, Tetraphenylantimony, and Tetraphenylbismuth Mesitylene Sulfonates Ph4EOSO2C6H2Me3-2,4,6 (E = P, Sb, Bi)

Шарутин

Шарутина²,

Сенчурин³

et al. 2022

Russ. J. Inorg. Chem.

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Organic Compounds of Bismuth: Synthesis, Structure, and Applications

Cited by 2 publications

References 187 publications

Construction of High‐Performance Anode of Potassium‐Ion Batteries by Stripping Covalent Triazine Frameworks with Molten Salt

Construction of High‐Performance Anode of Potassium‐Ion Batteries by Stripping Covalent Triazine Frameworks with Molten Salt

Synthesis and Structure of Tetraphenylphosphorus, Tetraphenylantimony, and Tetraphenylbismuth Mesitylene Sulfonates Ph4EOSO2C6H2Me3-2,4,6 (E = P, Sb, Bi)

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