Organic Electrochemistry in the USSR

Mairanovsky, V.G.

doi:10.1007/978-3-319-21221-0_9

Cited by 4 publications

(2 citation statements)

References 81 publications

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“…Such a study was the subject of one unrealised collective project, with the participation of V. Mairanovsky, Askold Engovatov et al, Institute of Vitamins VNIVI, Moscow, together with the Faculty of Technology of Semiconductors MITKCHT, Prof. Victor Fistul, cf. student´s work of Grisha Mayranovsky [63], [64] p.294.…”

Section: Scheme 3 Electrochemical Reduction Of 24-pentadienol and Its...mentioning

confidence: 99%

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A complex approach to study the electrode-solution region. Surface layer, electrical double layer, medium properties and chemical reactivity

Mairanovsky

2023

Preprint

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A complex approach to the study of the electrode-solution region is proposed that consists in the coupled study of molecular reactivity x and collective properties X. The general conclusion on the presence and value of the electrode effects for x is established by comparing the products of xdir, xhom of the direct electrolysis and the homogeneous catalytic ET- process HOMEC. The change in x with distance L from the electrode surface x = f(L) (1) is found by electrolysis using a near-electrode tomography NELTO by gradually varying the HOMEC´s contribution, the dependence (1) is established by solving the corresponding diffusion-kinetic equations. The collective characteristics X are related to the material and surface structure of the electrode, as well as the properties of the near-electrode medium - viscosity, dielectric constant, etc., which are measured by spectro-electrochemical and electrochemical-atomic force microscopy techniques; hence the dependence X=F(L) (2) is found. Some results, using previously published and also unpublished data, are given. The combined x, X - measurements and comparison of dependencies (1) and (2) open up new possibilities for establishing the nature of electrode phenomena

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Section: Scheme 3 Electrochemical Reduction Of 24-pentadienol and Its...mentioning

confidence: 99%

“….with the formation of the dianion M-M 2-(compare with the case of the ultrafast trans → cis following isomerization of the vitamin D "anion radical", by the concert{ei} mechanism, cf. [64]).…”

Section: Scheme 3 Electrochemical Reduction Of 24-pentadienol and Its...mentioning

confidence: 99%

A complex approach to study the electrode-solution region. Surface layer, electrical double layer, medium properties and chemical reactivity

Mairanovsky

2023

Preprint

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An approach to study the electrode–solution interfacial region. Direct vs. homogeneous electro-catalytic electrolysis, near-electrode tomography*

Mairanovsky¹

2020

J Solid State Electrochem

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Janis Stradins: An outstanding electrochemist. Part II: meetings, parallels, and intersections

Mairanovsky¹

2021

J Solid State Electrochem

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Organic Electrochemistry in the USSR

Cited by 4 publications

References 81 publications

A complex approach to study the electrode-solution region. Surface layer, electrical double layer, medium properties and chemical reactivity

A complex approach to study the electrode-solution region. Surface layer, electrical double layer, medium properties and chemical reactivity

An approach to study the electrode–solution interfacial region. Direct vs. homogeneous electro-catalytic electrolysis, near-electrode tomography*

Janis Stradins: An outstanding electrochemist. Part II: meetings, parallels, and intersections

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