“…Here we used a perylene bisimide chromophore substituted with a calix[4]arene unit ( oc , Chart ) as a novel molecular probe of polymer properties. We will compare its behavior with that of N , N ′-bis(2,5-di- tert -butylphenyl)perylene-3,4:9,10-bis(dicarboximide) ( oref ), a well-known fluorophore that has attracted considerable attention because of its high fluorescence quantum yield (Φ f = 0.99 in toluene, τ f = 4.0 ns), which forms the basis for its applications in various fields. , …”