Organic hybrid of chlorinated polyethylene and hindered phenol. III. Influence of the molecular weight and chlorine content of the polymer on the viscoelastic properties

Wu, Chifei; Yamagishi, Toshio; Nakamoto, Yoshiaki; Ishida, Susumu; Nitta, Koh‐hei

doi:10.1002/1099-0488(20001115)38:22<2943::aid-polb100>3.0.co;2-k

Cited by 32 publications

(19 citation statements)

References 26 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Recent years have seen the development of a series of organic hybrid composites of polar polymer/hindered phenols that might be served as high‐performance damping materials [13–19]. Energy dissipation resulting from dissociation of hydrogen bonding was proposed as a mechanism responsible for improvement in damping properties [20].…”

Section: Introductionmentioning

confidence: 99%

Hydrogenated nitrile butadiene rubber and hindered phenol composite. II. Characterization of hydrogen bonding

Cao

Mou

Shen³

et al. 2010

Polymer Engineering & Sci

Self Cite

View full text Add to dashboard Cite

This article reports on the relationship between the variation of hydrogen bonding and macroscopic properties of composites composed of hydrogenated nitrile butadiene rubber (HNBR) and 3,9‐bis {1,1‐dimethyl‐2 [β‐(3‐tert‐butyl‐4‐hydroxy‐5‐methylphenyl) propionyloxy] ethyl}‐2,4,8,10‐tetraoxaspiro [5,5]‐undecane (AO‐80). Hydrogen bonding of the composites was studied by Fourier‐transform infrared (FT‐IR) and ultraviolet (UV) spectroscopies. FT‐IR spectra at room temperature revealed that the stretching vibration peak of OH and CO of AO‐80 red shifted with increasing AO‐80 content, whereas that of C≡N of HNBR blue shifted only when the AO‐80 content exceeded 10 parts per 100 resin (phr). At elevated temperatures, the shift was the opposite for CO and C≡N bands resulting from hydrogen bonding dissociation. In the UV spectra, the E2 band of benzene ring of AO‐80 exhibited two peaks differing in shape. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers

show abstract

Section: Introductionmentioning

confidence: 99%

Hydrogenated nitrile butadiene rubber and hindered phenol composite. II. Characterization of hydrogen bonding

Cao

Mou

Shen³

et al. 2010

Polymer Engineering & Sci

Self Cite

View full text Add to dashboard Cite

show abstract

“…In general, the hindered phenol compounds have been usually employed as antioxidant additives for various polymers. Wu et al10, 11 investigated organic–organic hybrids based on rubbery chlorinated polyethylene materials and hindered phenol compounds. They found that addition of hindered phenol compounds to the polymer causes strong hydrogen bonding between hydroxyl groups of the hindered phenol and the α‐hydrogen of chlorinated polyethylene, resulting in the emergence of a shape memory effect under a relatively large deformation, which undergoes reorganization and recombination of hydrogen bonds.…”

Section: Introductionmentioning

confidence: 99%

Reinforcement of polyurethane‐based shape memory polymer by hindered phenol compounds and silica particles

Kuriyagawa

Kawamura

Hayashi

et al. 2010

J of Applied Polymer Sci

Self Cite

View full text Add to dashboard Cite

Reinforcement of polyurethane-based shape memory polymer materials was investigated by adding hindered phenol compounds and silica particles. According to dynamic mechanical analysis, these fillers had no effect on the glass transition temperature and the activation energy of soft segments, indicating that the fillers have no ability to influence the molecular mobility of soft segments. It was found from the tensile tests that the yield stress was increased primarily by addition of the hindered phenols rather than the silica particles, whereas Young's modulus was enhanced by the silica particles rather than the hindered phenols.

show abstract

“…AO-80 is a commercial antioxidant (ADK STAB AO-80; Asahi Denka Industries Co.). The glass transition temperature and melting temperature of AO-80 were 40 and 121C, respectively [14].…”

Section: Introductionmentioning

confidence: 99%

Effects of addition of hindered phenol compounds to a segmented polyurethane with shape memory on mechanical yielding

et al. 2010

Self Cite

View full text Add to dashboard Cite

The mechanical yielding behavior of the shape memory polyurethane (SMP) and its composite samples were investigated to verify the effect of addition of hindered phenol. The composite samples were prepared using SMP as matrix and hindered phenol (AO-80) as filler, and then tensile tests were carried out at a range of temperatures and with different fixed crosshead speeds. According to the tensile data at 25°C, the yield stress was increased by adding AO-80. In terms of the Eyring theory, the activation volume of deformation units decreased with increase of the amount of AO-80 added. This is because the packing of the hard segments is enhanced by addition of AO-80. Consequently, it was suggested that the yield process is caused by the rotation of hard segment domains within the deformed plastic domains composed of glassy soft segments.

show abstract

Organic hybrid of chlorinated polyethylene and hindered phenol. III. Influence of the molecular weight and chlorine content of the polymer on the viscoelastic properties

Cited by 32 publications

References 26 publications

Hydrogenated nitrile butadiene rubber and hindered phenol composite. II. Characterization of hydrogen bonding

Hydrogenated nitrile butadiene rubber and hindered phenol composite. II. Characterization of hydrogen bonding

Reinforcement of polyurethane‐based shape memory polymer by hindered phenol compounds and silica particles

Effects of addition of hindered phenol compounds to a segmented polyurethane with shape memory on mechanical yielding

Contact Info

Product

Resources

About