Organic–inorganic hybrid 1-D double chain heteropolymolybdates constructed from plenary Keggin germanomolybdate anions and hepta-nuclear Cu–RE–pic heterometallic clusters

Abstract

Two unprecedented 1-D double chain germanomolybdates containing hepta-nuclear Cu–RE–pic heterometallic clusters were prepared and the adsorption capacity of 1 toward dyes in aqueous solutions was investigated.

Various amide derivatives induced Keggin-type SiW12O404−-based cobalt complexes: assembly, structure, electrochemical sensing and dye adsorption properties

“…S4 †), which were monitored by measuring the intensity changes of the maximum UV absorption peaks of MB and NR solutions in the dark. 35,36 Complexes 1-3 showed good adsorption activities for MB with satisfactory removal rates of 92% for 1, 89% for 2, and 76% for 3 within 4-19 hours (Fig. 9a-c); the removal rates were 85% and 87% toward NR for 1 and 3, respectively, within 4-11 hours (Fig.…”