Organic–inorganic hybrid supermicroporous chromium oxophenylphosphate with magnetic and catalytic properties

Insights into mesoporous metal phosphonate hybrid materials for catalysis

“…Chromium oxophenylphosphate of fine microporosity and mesoporosity showed good catalytic activity in the liquid phase partial oxidation of aldehydes to the respective acids in the presence of dilute aqueous H 2 O 2 as an oxidant at room temperature, accompanied with certain stability after three times of cycling experiments. 127 In the presence of both the catalyst and peroxide, about 70% conversion of cinnamaldehyde was achieved.…”

First-principles study on the electronic, magnetic and spin transport properties of CU(6bpyNO)Cl2

“…The magnetism in organic-inorganic hybrid materials has attracted considerable research interest due to their potential in spintronic applications [1][2][3][4][5][6][7][8][9][10][11][12]. Recently, a new paramagnetic ligand, 2, 2'-bipyridin-6-yl tert-butyl nitroxide (6bpyNO) was synthesized, and then the compound Cu(6bpyNO)Cl 2 was obtained [13].…”