Organic-inorganic polyureas with benzyl hindered urea bonds and POSS cages in the main chains: Synthesis, shape memory and reprocessing properties

Wang, Huaming; Li, Lei; Zhang, Tao; Zheng, Sixun

doi:10.1016/j.eurpolymj.2023.112652

European Polymer Journal

2024

DOI: 10.1016/j.eurpolymj.2023.112652

|View full text |Cite

Organic-inorganic polyureas with benzyl hindered urea bonds and POSS cages in the main chains: Synthesis, shape memory and reprocessing properties

Huaming Wang,

Lei Li,

Tao Zhang

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 55 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Shape‐memory thermosets: Tailoring the structure for toughness improvement and scratch healability

Nguyen,

Truong,

Nguyen

et al. 2024

Polymer Engineering & Sci

View full text Add to dashboard Cite

A straightforward but effective approach to fabricate shape‐memory polyurethane thermosets by tailoring the soft phase composition of two‐ and four‐armed polycaprolactone (PCL) polyols is described. As the crystallization of the PCL soft phase has an effect on driving the self‐assembly of H‐bonds, a good balance of tensile performance and thermo‐healability can be achieved by regulating the ratio between PCL‐diol and PCL‐tetrol in the soft phase. The inferior ability of crystallization of the segments near the branching point gives rise to enhancement of the both overall healability and toughness of the network. Healings of punctured holes and cuts are assessed using optical microscopy (OM), field‐emission scanning electron microscopy (FE‐SEM), tensile analysis, and two‐electrode impedence characterization. The obtained network with the best healing behavior has a soft phase composition with the PCL‐diol/PCL‐tetrol molar ratio of 2/1, a tensile toughness of 64 MPa J−1 and a healing efficiency (estimated by recovery of tensile strength) of nearly 80%.Highlights The composition of the soft phase of polyurethane networks was tailored. Two‐ and four‐armed polycaprolactones were used for the network structure. A good balance between mechanical and healing performance was obtained. Healing of complete cuts showed tensile strength recovery of nearly 80%.

show abstract

Shape‐memory thermosets: Tailoring the structure for toughness improvement and scratch healability

Nguyen,

Truong,

Nguyen

et al. 2024

Polymer Engineering & Sci

View full text Add to dashboard Cite

show abstract

Green crosslinking strategy for ethylene-vinyl acetate rubber composites with NH2-POSS as a crosslinking agent and reinforcing nanofiller

Peng,

Zhang,

Duan

et al. 2024

Composites Science and Technology

View full text Add to dashboard Cite

Shape recovery and reprocessing of polyurethane networks crosslinked via host-guest inclusion complexation of adamantane with β-cyclodextrin

Xu,

Wang,

Zhang

et al. 2024

Reactive and Functional Polymers

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Organic-inorganic polyureas with benzyl hindered urea bonds and POSS cages in the main chains: Synthesis, shape memory and reprocessing properties

Cited by 3 publications

References 55 publications

Shape‐memory thermosets: Tailoring the structure for toughness improvement and scratch healability

Shape‐memory thermosets: Tailoring the structure for toughness improvement and scratch healability

Green crosslinking strategy for ethylene-vinyl acetate rubber composites with NH2-POSS as a crosslinking agent and reinforcing nanofiller

Shape recovery and reprocessing of polyurethane networks crosslinked via host-guest inclusion complexation of adamantane with β-cyclodextrin

Contact Info

Product

Resources

About