Abstract:In this work, we studied the effects of centenary Scots pine (Pinus sylvestris L.) afforestation on topsoil properties conducted in a deforested area that was previously occupied by a natural European beech (Fagus sylvatica L.) forest. Organic layers and topsoil Ah mineral horizons (0-10 cm) were sampled in the Scots pine and European beech forests of Moncayo Natural Park (north-eastern Spain). The physical (stoniness, aggregate stability, and water repellency persistence and intensity), chemical (total organic C, total N, C/N, pH, and exchangeable Ca 2+ , Mg 2+ , Na + , K + , Al 3+ , and Fe 3+ ), and physicochemical (cation exchange capacity) properties of soil were analyzed. Total organic C and N were also obtained for litter samples. The studied topsoils shared a series of common properties, such as a high stoniness and aggregate stability, very low base content, high cation exchange capacity, and extreme acidity. Soils that developed under the pinewood showed a higher soil water repellency intensity. However, K + content was significantly higher in the beechwood soil. In both forest types, total organic C and N were similar in topsoil and litter (Hemimoder type), although C and N were pooled in different O-layers. Results indicate that pine afforestation in a deforested area was an adequate measure for soil protection since it did not show significant differences in the long term (ca. 100 years) compared to the nearby natural beech stands.