Organic Microchemistry

Ogg, C. L.

doi:10.1021/ac60085a019

Cited by 4 publications

(1 citation statement)

References 59 publications

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“…However the latter species is paramagnetic and therefore leads to line broadening and unpredictable chemical shifts of nuclei interacting with it. The absence of the solvent signal in the 15 N NMR spectrum together with a massive low field shift of the proton signal of ammonia in the 1 H NMR spectrum to 27.82 ppm (pure NH 3 (l) exhibits a chemical shift of 0.20 ppm in the 1 H NMR spectrum) [66][67][68] is evidence for coordination of the ammonia and exchange between free and coordinated NH 3 . The absence of azide signals supports also at least partial coordination of it to manganese in solution.…”

Section: N Nmr Spectroscopymentioning

confidence: 99%

Ammine Complexes of Na‐, Ag‐, Mn‐, and Zn‐Azides

Müller

Buchner

Scheubeck

et al. 2016

Zeitschrift anorg allge chemie

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The synthesis of ammine metal azides is achieved through a simple route in liquid ammonia solution. Azides of silver, sodium, manganese, and zinc were obtained as ammine complexes from liquid ammonia and the solid compounds were characterized. The NH 3 solutions were investigated by means of NMR spectroscopy as well. The triamminesilver(I) azide as well as the unusual tetraamminesilver(I) 796and pentaamminesodium(I) azides are presented. The structures of the hexaamminemanganese(II) and hexaamminezinc(II) azides, which crystallize with four ammonia molecules of solvation, are elucidated. From these compounds the binary azides Mn(N 3 ) 2 and Zn(N 3 ) 2 were obtained by (careful) heating.

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Section: N Nmr Spectroscopymentioning

confidence: 99%