Organic Templated Cuprous Cyanide Open Frameworks Based on Cu₂(CN)₆ Dimer with Strong and Long-Lived Luminescence

Copper(I) and Silver(I) Coordination Polymers Based on Rigid Bis(triazole) Ligand: Syntheses, Structures, and Catalytic Properties

“…Atom Cu2 locates in a planar trigonal arrangement, where the metal atom is tricoordinated by N6 from a btb ligand, plus atoms N8 and C17 from two distinct CN – ligands. Mean bond lengths involving the cyanide ligands [Cu1–N7 = 1.973(5) Å, Cu1–C18A = 1.872(7) Å, Cu1–N3B = 2.052(5) Å, Cu2–C17 = 1.885(7) Å, Cu2–N8 = 1.970(5) Å, Cu2–N6 = 2.066(5) Å] are similar to those found in other copper(I) cyanides 22,23. The btb ligand adopts anti ‐conformation and the dihedral angle between the two triazole rings are 8.515°.…”

In situ construction of four copper(I) cyanide coordination polymers: crystal structures, fluorescence and catalytic properties

“…The sum of the different angles around the central copper(I) is 360°, indicating trigonal planar triangle geometry. Both Cu-N (1.934(4)-2.088(3) Å ) and Cu-C (1.899(4)-1.900(4) Å ) bond lengths are well matched to those observed in similar complexes [24]. The pair of CNligands acting in a l 2 -bridging mode bind two Cu(I) centers Transition Met Chem to form a Cu(CN) 2 subunit, which is further extended by l 2 -L4 ligands to form a 2D layer (Fig.…”

The three-dimensional coordination network in poly[di-μ3-cyanido-μ5-[5-(pyridin-4-yl)tetrazolato]-tricopper(I)]

“…It is worth mentioning that all five N atoms in the 4-ptz anion are coordinated to Cu I centres, with the four tetrazole N atoms coordinated only to Cu1 and the pyridyl N atom bonded only to Cu2. The CN À anion is coordinated via atom N4 to Cu1 at one end and, at the other end, via atom C5 to Cu1(x, Ày + 2, z + 1 2 ) and Cu2(x + 1 2 , y À 1 2 , z + 1) simultaneously, with a CuÁ Á ÁCu distance for this pair of Cu I ions of only 2.5306 (6) Å , which is comparable with some analogues (Qin et al, 2011;Zhou et al, 2009).…”