Die Organischen Katalysatoren Und Ihre Beziehungen Zu Den Fermenten 1935
DOI: 10.1007/978-3-642-91872-8_3
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Organische Schwermetall-Katalysatoren

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Cited by 4 publications
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“…Organocatalysis can be traced back at least a century to the enantioselective synthesis of quinine alkaloids. , Many enzymatic reactions are mediated by precise arrays of organic functional groups, and much of the early work was inspired by an effort to understand and mimic the remarkable rates and selectivities of enzymatic catalysis. The application of chiral organocatalysts for enantioselective synthesis has, ,, particularly in the past decade, spawned an impressive array of new catalysts, processes, and mechanistic insights. While the focus of most recent research in organocatalysis has concentrated on enantioselective synthesis of small molecules, organocatalysis offers a number of opportunities in polymer synthesis and was among the earliest methods of catalyzing the synthesis of polyesters …”
Section: Introductionmentioning
confidence: 99%
“…Organocatalysis can be traced back at least a century to the enantioselective synthesis of quinine alkaloids. , Many enzymatic reactions are mediated by precise arrays of organic functional groups, and much of the early work was inspired by an effort to understand and mimic the remarkable rates and selectivities of enzymatic catalysis. The application of chiral organocatalysts for enantioselective synthesis has, ,, particularly in the past decade, spawned an impressive array of new catalysts, processes, and mechanistic insights. While the focus of most recent research in organocatalysis has concentrated on enantioselective synthesis of small molecules, organocatalysis offers a number of opportunities in polymer synthesis and was among the earliest methods of catalyzing the synthesis of polyesters …”
Section: Introductionmentioning
confidence: 99%
“…Almost a century after its beginnings, the field of organocatalysis has undergone a resurgence with the development of new classes of highly enantioselective organocatalysts. Notwithstanding the extraordinary pace of developments in transition metal and organometallic catalysis, , it is clear that organocatalytic reactions have evolved to provide a powerful addition to the armamentarium of methods for chemical synthesis. Organocatalysis has also proven a powerful strategy for polymer synthesis . We have investigated a variety of nucleophilic and basic organic molecules as catalysts for transesterification , and ring-opening polymerization reactions (Figure ) .…”
Section: Introductionmentioning
confidence: 99%
“…Dakin in 1909 demonstrated that in a Knoevenagel type condensation between aldehydes and carboxylic acids or esters with active methylene groups, the amine catalysts could be mediated by amino acids [75]. Langenbeck is remembered for developing enamine type reactions and the application of simple amino acids and small oligopeptides as catalysts [76][77][78]. Natural products, in particular, strychnine, brucine, and cinchona alkaloids and amino acids (including short oligopeptides), were among the first organic catalysts tested [79,80].…”
Section: Discovery and The History Of Organocatalysismentioning
confidence: 99%